Electrochemical behaviour of Cu-Ni alloy in 3%NaCl medium polluted by sulphides: effect of aminotriazole
Identifieur interne : 000337 ( France/Analysis ); précédent : 000336; suivant : 000338Electrochemical behaviour of Cu-Ni alloy in 3%NaCl medium polluted by sulphides: effect of aminotriazole
Auteurs : A. Laachach [Maroc] ; A. Srhiri [Maroc] ; C. Fiaud [France] ; A. Benbachir [Maroc]Source :
- British Corrosion Journal [ 0007-0599 ] ; 2001.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
The behaviour of 70/30 Cu-Ni alloy in 3%NaCl medium, both pure and contaminated by 1 ppm S2- ions, has been studied in the absence and in the presence of aminotriazole at a concentration of 10-4M. Potentiodynamic and electrochemical impedance measurements showed that sulphides accelerate the corrosion of the alloy in 3%NaCl. The aminotriazole inhibited both anodic and cathodic corrosion processes. The inhibiting effect was higher when the solution contained the S2- ion Analysis by scanning electron microscopy (SEM) showed that the inhibitor acts by establishing a very thin film on the metal surface. This film behaves as a barrier to the diffusion of dissolved oxygen and to the transport of the metal ions from the melt to the solution.
Affiliations:
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Pascal:02-0223594Le document en format XML
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<term>Corrosion protection</term>
<term>Corrosion rate</term>
<term>Electrochemical corrosion</term>
<term>Impedance</term>
<term>Nickel alloy</term>
<term>Sodium chloride</term>
<term>Sulfides</term>
<term>Triazole derivatives</term>
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<term>Sodium chlorure</term>
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<term>Triazole dérivé</term>
<term>Impédance</term>
<term>Vitesse corrosion</term>
<term>Accélération</term>
<term>Alliage base cuivre</term>
<term>Protection corrosion</term>
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<term>Alliage CuNi</term>
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<front><div type="abstract" xml:lang="en">The behaviour of 70/30 Cu-Ni alloy in 3%NaCl medium, both pure and contaminated by 1 ppm S<sup>2-</sup>
ions, has been studied in the absence and in the presence of aminotriazole at a concentration of 10<sup>-4</sup>
M. Potentiodynamic and electrochemical impedance measurements showed that sulphides accelerate the corrosion of the alloy in 3%NaCl. The aminotriazole inhibited both anodic and cathodic corrosion processes. The inhibiting effect was higher when the solution contained the S<sup>2-</sup>
ion Analysis by scanning electron microscopy (SEM) showed that the inhibitor acts by establishing a very thin film on the metal surface. This film behaves as a barrier to the diffusion of dissolved oxygen and to the transport of the metal ions from the melt to the solution.</div>
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