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Electrochemical behaviour of Cu-Ni alloy in 3%NaCl medium polluted by sulphides: effect of aminotriazole

Identifieur interne : 000337 ( France/Analysis ); précédent : 000336; suivant : 000338

Electrochemical behaviour of Cu-Ni alloy in 3%NaCl medium polluted by sulphides: effect of aminotriazole

Auteurs : A. Laachach [Maroc] ; A. Srhiri [Maroc] ; C. Fiaud [France] ; A. Benbachir [Maroc]

Source :

RBID : Pascal:02-0223594

Descripteurs français

English descriptors

Abstract

The behaviour of 70/30 Cu-Ni alloy in 3%NaCl medium, both pure and contaminated by 1 ppm S2- ions, has been studied in the absence and in the presence of aminotriazole at a concentration of 10-4M. Potentiodynamic and electrochemical impedance measurements showed that sulphides accelerate the corrosion of the alloy in 3%NaCl. The aminotriazole inhibited both anodic and cathodic corrosion processes. The inhibiting effect was higher when the solution contained the S2- ion Analysis by scanning electron microscopy (SEM) showed that the inhibitor acts by establishing a very thin film on the metal surface. This film behaves as a barrier to the diffusion of dissolved oxygen and to the transport of the metal ions from the melt to the solution.


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Pascal:02-0223594

Le document en format XML

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<term>Electrochemical corrosion</term>
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<div type="abstract" xml:lang="en">The behaviour of 70/30 Cu-Ni alloy in 3%NaCl medium, both pure and contaminated by 1 ppm S
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ions, has been studied in the absence and in the presence of aminotriazole at a concentration of 10
<sup>-4</sup>
M. Potentiodynamic and electrochemical impedance measurements showed that sulphides accelerate the corrosion of the alloy in 3%NaCl. The aminotriazole inhibited both anodic and cathodic corrosion processes. The inhibiting effect was higher when the solution contained the S
<sup>2-</sup>
ion Analysis by scanning electron microscopy (SEM) showed that the inhibitor acts by establishing a very thin film on the metal surface. This film behaves as a barrier to the diffusion of dissolved oxygen and to the transport of the metal ions from the melt to the solution.</div>
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